Actually PVC hose will break down in water at lower temperatures, given the right conditions (dissolved material and temperature) this accelerates the process (hence why I keep asking what he did to the hoses to sanitise).
The rating is usually determined by what the end use is and an acceptable rate of breakdown for that use. Although the ratings can be for different objectives as QB was saying.
Contrary to what others (GB?) would have you believe, there is no "sudden" magical temperature at which PVC will suddenly leach huge amounts of plasticiser or monomer...it is a gradual thing.
I highly doubt 5 minutes of running 90-95 degree wort through a tube is going to leach enough plasticiser from a 65 degree rated hose to be discernable in 20 L, unless of course that the hose is already starting to breakdown...sit the hose in the sun full of water all day or boil it in water and you will, but this is not what he is Foles is doing...is it?
Silicon hose is just a little more resilient to these processes...if Foles can kill two bits of PVC hose before he attaches them to his brewery, I believe he will also kill the Si hose and end up with the same problem...
Ho Hum, you try to help and get berated...