Don't forget that BoPils was traditionally mashed with a phytase rest, I can't see why using Acidulated malt in place of that would be a bad move, perhaps adding CaCl if you normally have conversion problems . I can't really believe that using the 5.2 buffer is necessary, and if noone knows what's in it, why would you use it?
Because it does everything that CaCl2 does and more, but reputedly without contributing any mineral flavours. Hence, the attraction for lagers. In principle, it could also come in handy when mashing large amounts of specialty malts, as there would be no need to read colour changes in dark wort when adjusting the pH upwards.
OTOH, if 5.2 is an inorganic salt, then it must be contributing minerals, with Na, K, Ca or Mg the most likely candidates. Another possibility is that it is a blend of ammonium salts, which I tend to think would be a bit of a mixed blessing. These might not contribute so much flavour, but it could be a case of excess nutrient (depending on the quantities used). The final possibility is that 5.2 is an organo-phosphate, which might solve the mineral hardness problem. In fact, malt contains just such a substance - it is the phytate that phytase rests exploit.
Brace yourself FGZ, I'm about to speak in tongues again :icon_cheers: . Here's the reaction that causes calcium additions to acidify the mash:
3Ca++ + 2HPO4-- <-> 2H+ + Ca3(PO4)2
So, calcium reacts with biphosphates in the malt, precipitates phosphates and releases acid. If CaCl2 is used then the acid released is HCl, whereas if CaSO4 is used then the acid is H2SO4. This raises an interesting conundrum: HCl is highly volatile at mash temperatures, and so would be expected to evaporate off. Presumably, it reacts with other stuff in the malt in order to preserve its effects. But note that if 5.2 is some blend of calcium biphosphates, then it would effectively be mirroring what occurs naturally anyway.
Can a kind soul with some 5.2 perform a simple test? Try to dissolve about a tablespoon in half a cup of cold water. Let us know whether its dissolving power is more like gypsum (CaSO4) or more like table salt (NaCl). If it's too soluble, I would start to get nervous ...