Just to clarify,
we are talking about two completely different substances, one is a natural hop extract the other is a synthetic organo-silicate
Hop Anti Foam
MSDS
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Product Info Sheet
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This is a heavy oily waxy substance extracted from hops when they are processed into hop products like Iso-Alpha, Tetra Hop, and Hop Oils etc.
Being made entirely out of Hops when it is used in the kettle it breaks down and is left in the kettle with the trub. There is no possibility of it getting into the fermenter and in any way affecting the beer.
On the down side, it is totally useless in the fementer, it simply isn't made for the job, there is a matching Fementer Anti Foam also made from hops, it is a major PITA to remove if you aren't filtering your beer with a commercial (style) DE filter.
My trials didn't encourage me to stock it, although I think would be excellent for commercial breweries trying for the more natural beer experience.
Silicone Anti Foam
History Wiki Link
Defoamer Link
White slightly oily water dispersible liquid synthesised from Silicon (the Element) and organic molecules.
Silicone is man made and is persistent, meaning that it wont break down in the kettle or the fermenter and is only very slowly degraded in nature (can be a waste disposal issue).
It will carry on through each step in the brewing process. If you are using this product you must insure that you remove every trace of it before you package your beer or it can kill the head.
Fortunately it has a high affinity for DE (Diatomaceous Earth), Keiselguhr, Perlite and Cellulose fibbers: in other words all the products used for commercial filtration of beer.
The big advantage Silicone has is that it's very effective in the Fermenter as well as in the kettle.
Of the two the silicone product is the most effective, if you are aware of the potential problems and exercise due care it can be a very useful tool.
I prefer the natural Hop Anti Foam, but it's just that a preference.
MHB