When you see boil oFf expressed as a percentage, there is a reason for that.
% boil off is an indicator that your boil is vigorous enough to be doing all the things like protein coagulation and evaporating volatiles that it is supposed to do. Percentages are however a lousy way to try and work out your likely pre and post boil volumes.
The amount you boil off per hour, will stay relatively static... If you have the same pot and you do not adjust the amount of heat you apply to the pot. However, depending on your actual boil off rate and the boil vigor you get, you might actually want to adjust the amount of heat.
You should be boiling off somewhere between 15 & 8 % of the starting volume of your kettle in an hour. This indicates that you are doing everything that needs to be done in the boil, but you aren't sticking in too much heat... Which can also be less than optimal for your beer quality.
So - if for instance you were getting 12% boil off in A single batch... Then decided to do a double batch and make no changes to your heat. Firstly, I think its obvious that more liquid, but no more heat, will mean a more "gentle" boil, this will reduce the actual amount boiled off per hour by an amount, and you start with more liquid, so the % boil off is halved. All in all what was a 12% boil off in a single batch, will become less than a 6% boil off in a double batch - and that's not really enough. Plus you have a more gentle boil, maybe too gentle.. You simply aren't shoving in enough units of energy into every liter to do the job of "wort boiling" properly.
So you turn up the heat... And despite what people so frequently say, if you turn up the heat, you do increase both the vigor of the boil and the amount of liquid boiled off per hour.
You need two things from a boil... {a} that it's is visibly rolling, churning & bubbling {b} that it boils off at least 8% of the starting volume per hour. And it's probably best practice to apply as little heat as possible to the system in order to get that result. Just because 8% an hour is a "minimum" doesn't mean you should just target 25% per hour on the more is better theory. More is not necessarily better. 8-15% is the "safe zone" where you know for sure you have are doing enough, but not too much.
Once you know that your boil looks good and that your percentage boil off is in the safe zone. Then - your life will be a hell of a lot easier if you just think about you boil off as a liters per hour figure. Before that, to just say "your boil off will stay the same no matter what your boil size" or sentiments to that effect - is overly simplistic, not quite accurate, and IMO, not very good advice.
Nicely - while your standard 20% per hour is a bit high (don't fritz out too much, it's not ideal but it's not a tragedy either, high is way better than low) it does mean that at 11% for a double batch, that you are smack in the middle of the target range. All you have to do is tweak your expected volumes and you're cooking (probably literally) with gas.
TB