Lyrebird_Cycles
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yankinoz said:Re Tritan, Eastman's tech sheet gives an oxygen transfer rate in 24 hours of 32 cc oxygen per cubic metre of a barrier 0.1 mm thick.. That's at a one-atmosphere partial pressure differential, which is about what you'd expect between the outside air and an oxygen-free, unpressurised fermenter. If the walls of the "Catalyst" are 5 mm, the rate would be 1.6 cc/sq meter in 24 hrs. That's not negligible.
It looks like Tritan is meant to cash in on worries about bisphenol leaching from container walls. That's a debate in its own right.
The partial pressure difference used for diffusion calculations is that of the diffusant, which in this case would be about 21 kPa, being nearly zero* on one side of the barrier and 21 kPa on the other. Assuming an area of about 0.3m2 and walls around 5mm, the stated rate of 32 ml / m2 / day comes out to an oxygen ingress rate about 62mg per day or 2.5 ppm per day for a 25 litre brew. Not a problem during fermentation but completely unsuitable for storage.TSMill said:1 atmosphere partial pressure differential is approximately 100kPa, so more analogous to a keg than an unpressurised fermenter. Similar to HDPE, I cannot imagine this has an appreciable oxygen ingress rate over the course of a typical fermentation.
* figure 2 kPa per ppm DO2 but in most fermentations the DO2 is well below that.