Appreciate people's input, there are some good sources and I'm reading up. Thanks manticle esp for your input and article.
Put basically, and from what ive read, water chem is no more or less complex than learning about mashing basics. With every brew things improve and the more I read, the more little mistakes arr corrected.
My original post was more a question as to why water isn't discussed more often, but seems I was wrong. But, I'm surprised still that is not discussed more. And is only a rare recipe I see people adding salts etc. Or discussing it as part of a recipe aim - ie. Hardness, calcium, sulfate levels etc. Yep, I'm nerding out, and really keen to see what some basic chem can do, keep reading and keep learning.
Guess as cb said, I'm gonna give it a go and at the end, I'll still have beer.