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MB the method of doing it with the original wort is the way to go IMO. Thereby conserving the original profile. A schott bottle or similar would be fine i guess. Just need to keep the small volume to the side while the large volume cools to the target temp... something like a small NC cube.
Argon,
Could you not simply cool the whole cube (23L) to 4 C as per your method, then when you add the wort to the fermenter take 3L from the fermenter tap (or directly poured from cube) and raise this to the boil, add hops and add to fermenter to get fermentation temperatures. Why do you need to keep a separate sample?
I generally air rate with an aquarium pump which takes an hour and figure you could do the aroma hop while this is going on.