Interesting discussion once again chaps! :icon_cheers:
Yes, sometimes I wonder if I'm kidding myself about the degree, if any, of a caramel flavour change. However, I think the variability in the results is partly explained by different endpoint for anyone who tries it as there isn't a gauge or measure for when to actually stop caramelising. Every brewer will have a different endpoint with this caper, and I think many brewers have stopped too early in their process for any real benefits, my conclusion is that it needs to be almost smoking to be having any effect.
The fact that maltose caramelises at 180C is probably quite important, I suspect many brewers have not come close to this temperature, although there are probably other sugars caramelising at lower temperatures that could be contributing to the flavour profile and perhaps in varying proportions. I would like to measure the actual temperatures (with a candy thermometer) achieved in the process the way I do it, just haven't got around to it. I don't doubt there's a discernable flavour shift (and obviously some colour but that's immaterial to me), lending some repeatability to the process would be one way to put a lot of the debate to bed, the best I can do so far is to stop when it starts to smell like it is about to burn.
I'll post some pics next time I do it with wort, today I did the caramelised DME effort mentioned earlier, some pics...
So, this is how it looks at the beginning, about 1/2 a cup of hot water with 200g of Coopers' Dried Malt Extract:
About half way through. Frothing is obvious, but the stuff is sticking to the sides of the pot and forms a sort of honeycomb (confectionery)/ styrofoam texture, not just the thick sticky liquid any more.
The end point today. Note the consistency, I don't usually take it quite this far, it has formed a mass rather than being just a sticky goo in the bottom of the pan. There's a distinct almost- burning odor, not really smoky though. I'm expecting this to have more of a Caraaroma flavour and aroma.
The wort I've added this to is actually 100% Bairds Perle/ Pale Ale with just a mashout decoction, I'll post a hydrometer sample pic when its finished the boil. I started this caper trying to emulate TTL which supposedly has 100% GP, some caramelised wort and 1469, but I think now that I'm more into TTL- inspired ESBs.
:beer: