There appears to be alot of confusion in this thread about different events at the start of the boil.
Tendency to boilover At the start of the boil, due to dissolved gases coming out of solution from the liquid, you get lots of foaming, especially if you throw in some pellets. Also, because the amount of heat is high, to bring the kettle to the boil, higher than actually needed to maintain the boil, the foaming can quickly rise up and overflow. Common methods to combat this are to bat the foam down with the paddle, a spray bottle or turn the heat right down.
Scum at the start of boiling This is a grey scum, very similar to that on the top of the mashtun after recirculating. If it is not removed, it sinks back into the wort after about 10 minutes. Some people skim it off, some don't. Skimmers say the end result is a cleaner flavoured beer. Often, a small boilover at the very start removes this.
Hot break This forms in wort as it is heated and starts at about 80 deg C. It has nothing to do with the grey scum or the boiling action. It is often not obvious in the kettle due to the depth of the wort and the foam on the surface. Anyone who has made some starter wort up in a saucepan will have seen it form. It is removed along with hops as part of the whirlpooling action at the end of the boil. It is not wanted in the fermenter and most brewers aim for 100% removal from the fermenter. Many brewers who use whole hops and whirpool report that the hops provide a good filter bed for the removal of the hot break.
Cold break Not really relevant to the original boiling, but to complete the picture, cold break occurs when the wort is rapidly chilled.
From discussions some time back on HBD, the ideal amounts of each into the fermenter are: Scum 0%, hot break 0%, cold break 10%.
A small amount of cold break was actually found to be beneficial to the final beer, as some of the cold break provides nutrients to the yeast during fermentation.
To achieve good hot break formation and removal, maintain a good boil and whirlpool at the end. To achieve good cold break removal, chill rapidly, allow to settle in fermenter for 30 minutes, then rack to another fermenter.