Just to clarify things as to what I am hoping to achieve, I was researching on ways to overcome the inherent problem with using a CO2 extinguisher as a kegging cylinder, namely that the O ring in the valve pin eventually fails as it was not designed to hold pressure for long periods or (many) repeated uses. I was open to many ways of overcoming this, from using screw down valves rated for CO2 at typical cylinder pressures, through to using a slightly larger O ring to give a tighter seal and retain pressure longer.
In all these ideas, I have been communicating with the licensed filler who has worked with fire extinguishers for many many years. He is no fool, and would not agree to anything that would be dangerous or suspect in his opinion. He sees that using a screw down valve may be quite suitable, and this has been done by other licensed fire extinguisher refitters/refillers with success. However, the valves are hard to come by these days, and there are many different threads to deal with also, so this may not be the best way to pursue the matter.
On the other hand, if the original O ring could be *safely* replaced with one that is slightly larger, and therefore able to give a better seal for a longer amount of time, then what is the harm? Fire extinguishers used for kegging seem to eventually leak through the O ring, so if the larger one leaks eventually you are still in the same position you were before, but if it can seal long enough to allow the gas to be used before it fails, then it can simply be replaced at each filling. A larger O ring is not likely to cause any other issue that I can see, as long as it is able to travel up and down the tunnel without deforming in the process.
As always, I will discuss the use of the larger O ring with the licensed refiller first.
Crundle