Hashie
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It is known that oxidation plays an important part in the formation of protein haze and that compounds known as melanoidins function as anti-oxidants and prevent the oxidation of protein. Oxidation also plays an important part in the production of colloidal haze, hence the name "oxidation haze", first coined by Helm, the German brewing scientist, in early part of this century.
Moreover, the formation of chill haze is also considerably increased by oxidation. Chill haze occurs in finished beer during cold storage, the chill haze will disappear if the beer is warmed (this is only viable if the beer is to be consumed immediately, if the beer is chilled again the haze will return). Later the beer will throw an irreversible haze at ordinary temperatures. Permanent haze is the end product of chill haze. If you get chill haze permanent haze will follow in time.
The oxidation of melanoidins will result in a lower quantity of stable colloids. Unstable colloids promote chill haze and permanent haze in beer. Conversely, the presence of stable colloids inhibits chill haze. The stability of beer colloids is the result of a very complex equilibrium, and the whole problem of colloidal haze formation is very complex. A better understanding of this problem will show it possible to take some steps to minimize its effects in finished beer.
Work done by Jean De Clerk, the famous Belgian brewing scientist has shown that darker beers are inherently more stable and clear. De Clerk attributed this to the presence of large amounts of melanoidins found in darker grains.
Melanoidins were first discovered by the French chemist Maillard, the reaction between amino acids and sugars which form these substances is know as the "Maillard reaction".
By definition, melanoidins are stable complexes formed at high temperatures (i.e. mash out temps.), they are colloidal in nature and are powerful reducing agents and give an acid reaction in aqueous solution. melanoidins are reddish-brown colored substances with a characteristic aroma (malt).
Color and aroma are not the only traits that melanoidins contribute to a beer. Their colloidal nature enables them to "protect" unstable colloids present in beer and to prevent haze formation. At the same time, melanoidins are powerful reducing agents and this too can prevent beer from throwing a haze. In addition the acid character of melanoidins helps improve the quality of beer.
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