Thirsty Boy
ICB - tight shorts and poor attitude. **** yeah!
- Joined
- 21/5/06
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Up front I going to say I'm a bit of a sceptic especially where people talk about Aroma, taste well that's pretty straight forward and yes First Wort Hoping can give a smoother beer, the mechanism is even well enough understood. Alpha Acids (remember that there are three of them) are as we all know relatively insoluble cold but are quite soluble in hot wort, in solution over a given time a proportion of them will Isomerise and once Isomerised a proportion of those will undergo "Trans Isomerisation Degradation" what governs the rate of both reaction is heat. Simply in hot wort Alpha Acids go into solution, the hotter it is the faster they get isomerised and the faster Iso-Alpha breaks down, it's the Iso-Alpha breakdown products that contribute to the smoother bitterness.
By adding hops earlier in the kettle they have more time to undergo the process; you get more Trans-Iso products giving smoother tasting beer. If you were doing 90 minute or longer boils I suspect that there would be very little difference to the taste, but getting the hops in 15-20 minutes earlier in a shorter boil would make a marked difference.
For those that care "Isomerization and Degradation Kinetics of Hop (Humulus
lupulus) Acids in a Model Wort-Boiling System " MARK G. MALOWICKI AND THOMAS H. SHELLHAMMERView attachment 52660
Where it comes to aroma, well that's where I get very sceptical, to be able to smell something it must be volatile, anything volatile that's been in the boil for an hour or more has been ejected it's gone you won't be able to smell it! Talk about aromas being "locked in" doesn't make much sense either, unless someone can explain how they later get unlocked and become volatile again. Much more likely that as the hops were boiled longer there has been more volatile products stripped out so later additions are more easily detected.
I have no doubt that FWH changes the beer, I think we even know how, that hops boiled for an hour or more add anything much to hop aroma I doubt.
Mark
Actually - a fair few aroma compounds are released in "beer" that are bound in wort. Specifically (but limited to as far as I am aware) degredation products of glycosides from hop products. There is a bunch of chemistry involved which is way over my pathetic arm waving understanding - but it certainly makes sense to me that aromas which might (in a VERY arm waving type of fashion) get baked into low temperature wort in a way that binds them to other compounds, the result being able to survive being volatilised in teh boil... but which are helpless in the face of the enzyme rich, low pH, mild ethanol solution which happens in your fermenter.
Beer is chemically very different to wort - things which are "done" in wort can and always are, "undone" in beer and the results may well be smelly.
I'm not saying that I am a FWH believer - I dont really have an opinion one way or the other - but its certainly conceivable to me that the process could result in different proportions of compounds that break down to release aroma in a beer. Especially given that my understanding of what FWH is supposed to do to aroma is make it "long lasting" so when other aromas have faded away... FWH have an aroma that lasts over time. If things are being slow released as they break down in beer, that would explain it.
This doesn't talk at all baout FWH - but it does demonstrate the idea of aromas being released over time in a beer due to the breakdown of hop compound glycosides.
http://hopsteiner.com/pdf/gly_bound.pdf
TB