Here is an Article I did in 2016 on diacetyl
Note: new studies after I did this article are saying now when dry hopping, second diacetyl rest is needed.
A lot of brewers would consider it a flaw.
All through some classic beer styles call for low levels of diacetyl. Which gives off a buttery or butterscotch aroma and flavour. Some beer drinkers actually find diacetyl to be enjoyable
So what is Diacetyl,
It is a small organic compound that belongs to the ketone chemical family that is derived from yeast in the fermentation stage as a by-product.
Formual (CH3CO)2
In the 1950's diacetyl levels were found in the range of 0.2 to 0.3mg/l. Today it's about 0.05mg/l
So how does it happen,
All brewers yeast stains produce it, some more than others like high flocculent yeast stains. And others have the ability to absorb and reduce diacetyl. Fermentation problems like control of temperature can also affect the diacetyl levels.
Higher the temperature results in faster yeast growth and acetolactate. The higher the acetolactate peck, the higher the diacetyl peck but higher temperature also increases diacetyl reduction.
Lower yeast growth rates can reduce the amount of acetolactate produced, it can result in higher level of diacetyl in the finished beer if the lower growth rate results in lacklustre fermentation.
It is often beers that ferment more slowly and produce less acetolactate that have problems since to yeast are still slowly producing acetolactate late into fermentation.
The vanilla tone which is often confused with caramel flavouring, definitely adds to the smoothness of the beer. The problem is that diacetyl at these levels is unstable and eventually will turn into headspace air. As consequence, these beers typically have a short shelf life and do not travel well.
The other ketone of interest is 2,3 pentanedione which together with diacetyl forms a beer's vicinal diketones (VDK) aromatic volatile compounds.
So what can I do prevent it
- As always go overboard with your sanitation from start to finish
- Make a healthy yeast starter at least four days out from brew day,
- BeerSmith is a great program that gives you the recommended stater size.
- Two days out from brew day chill your stater to 6c to settle the yeast.
- At the end of brew day when chilling your wort have it 2c below your target Fermentation temperature.
- When Pitching only pitch the yeast slurry.
- 24 hours after pitching increase the temperature by 1c, 48 hours again by 1c. You how should be at your target temperature.
- On the last two days of Fermentation increase the temperature by 2c, this will absorb the diacetyl.
- Carry out force diacetyl test or VDK
- At the end of Fermentation cold crash, your beer slowly over days down to 3c and hold or another day.
- Bottle or keg your beer as normal.
I hope this has helped you in your pursuit of brewing better beer
Cheers
Sandgroper
(George Copley)