Ok So I have Found some SCIENCE!!!!
http://www.aussiehomebrewer.com/forum//ind...st&id=36896
Although the document only refers to temps above 90C.
So here are a few exerts from it.
Comparisons
between the model system and actual wort showed a significant
decrease in utilization when actual wort was used (49%
utilization for model system, 24% for wort). Utilization was
shown to decrease with increasing wort gravity, and a large
portion (51%) of the iso-alpha acids formed was found to be
present in the hot break.
Laufer and Brenner (5) also traced losses of bitter acids during
wort boiling and throughout the process to finished beer, finding
38% loss to trub, 35% to spent hops, and 10% to yeast and
covers.
The rate of conversion of alpha acids to iso-alpha acids was
highly dependent on temperature (Figure 4). For typical 100
C boiling conditions, 77% of alpha acids were isomerized
within 120 min. Temperatures of 130 C isomerized 100% of
alpha acids within 30 min of heating. A 90 min boil at 100 C
corresponded to a final iso-alpha acid concentration equal to
60% of the starting alpha acid concentration.
The results obtained indicate that the rate of isomerization
roughly doubled for every 10 C increase in temperature
(average change was 229% per 10 C increase).
Meaning approximatly half for drop of 10C
High temperatures quickly
led to degradation products, as evidenced in the dramatic
decrease of iso-alpha acid concentration beyond 18 min of
heating at 130 C.
While the rate of isomerization slowed at
temperatures below 100 C, substantial amounts of iso-alpha
acids were still produced at 90 C. This is significant if hot
wort is held at temperatures just below boiling after the kettle
boil is completed, while in the whirlpool, or awaiting transfer
to a heat exchanger.