Nick JD
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I just made some dark candy sugar last night. I used 2.5kg of white sugar, citric acid and some DAP (yeast nutrient). I read somewhere that DAP is added for nitrogen which reduces the temperature for the maillard reaction to start. This should mean you have more leniency in terms of darkening it without risking getting too close to burning it.
I started with nearly no water until the sugar was partially melted then I added boiled water. in the past I've added too much water at the start and it took ages to boil it off.
I did half quite dark, and half between amber and dark
We need a chemist to chime in, but I have a feeling that using DAP actually allows mailard reactions, not just caramelisation.