leiothrix
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Not to be picky or anything, but boiling alone isn't enough to sterilize.Yes there is a good reason... iodophor and the like sanitise, not sterilise.
Wikipedia article
Boiling in water for 15 minutes will kill most vegetative bacteria and viruses, but boiling is ineffective against prions and many bacterial and fungal spores; therefore boiling is unsuitable for sterilization. However, since boiling does kill most vegetative microbes and viruses, it is useful for reducing viable levels if no better method is available.
Wanting to avoid the chemicals is fair enough though.
I did think of a reason to boil - if you have a large jar and want to fill it with a hot sauce (hot as in temperature), pouring that into a cold jar is not the cleverest thing to do.