als_world
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It's only chlorine based products that pit stainless steel. Napisan is sodium percarbonate based (http://en.wikipedia.org/wiki/Sodium_percarbonate) which releases hydrogen peroxide when mixed with water which then produces the oxygen bleaching effect.
I normally soak my kegs in napisan for a day or so to loosen up the gunk and then give a scrub out. I then mix up 4 litres or so of 1:1000 idophor, give it a few PSI of CO2, shake it around and give each of the posts a quick squirt out. Then I leave the rest of the iodophor in the keg under CO2 pressure until it's next use. After a couple of weeks the iodophor has decomposed to leave a clear liquid.
I normally soak my kegs in napisan for a day or so to loosen up the gunk and then give a scrub out. I then mix up 4 litres or so of 1:1000 idophor, give it a few PSI of CO2, shake it around and give each of the posts a quick squirt out. Then I leave the rest of the iodophor in the keg under CO2 pressure until it's next use. After a couple of weeks the iodophor has decomposed to leave a clear liquid.