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Add it whenever you like. Some point in the boil is probably a good idea.
The yeast couldn't care less.
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I get excellent head from some extracts. I think it's worth a shot. Good call, @trustyrusty.
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The rainwater is just what I have at my house, it tastes great and it's just not really something I'd like to do to go and buy bottled...
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It's definitely not a blank state, depending on where you live you could have lots of NaCl (near the sea), lots of various chlorides...
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