It isn't, the information on the bottle relates to the bottle but not the valve. When you do run out of gas, its a really good idea to write the EW on the bottle somewhere with a good permanent marker.
The markings on the bottle are all there for testing.
The 4L is the volume of the bottle, also often expressed as W.C. (water content), the CO2 fill mass is WC*0.66 = 2.46kg
They need that information for bottle testing, where they fill the bottle up with water, pressurise it to a standard pressure (depending on the gas the bottle is being used for), relieve the pressure and check that the bottle hasn't grown.
The bottle mass has to be right to, if it falls the tester assumes its rusting/corroding and will fail the bottle.
Mark