Hi Ross
My understanding is that isomerisation is not just a function of heat, but is also dependent on the physical movement of the hops. This is achieved through a rolling boil. When you turn the heat source of the physical movemnet quickly stops and so does any significant isomerisation. I asked TDH from Grumpys about this. They brew 10 000 litre batches so their beer takes quite a bit of time to cool. During this time, the wort remains in contact with the hops. He said that once the boil was over this contact added little to the overall bittering.
I also wouldn't bother removing the bittering hops, as by the end of the boil, they've basically given up most of the bitterness. The increased hops utilisation bewteen a 60min boil and a 90min boil is negligible, so I would think the increased utilisation between a 60min boil and 30mins of the bittering hops just steeping would be even less. If anything is going to add to the bittering it would be the late additions, in particular any flame out additions, as the utilisation in the first 10-15 minutes is quite high in comparison. But as I already said, I doubt it would add much as isomerisation is a function of both heat and physical movement.
I would be looking at other reasons for the increase in bittering. Maybe fresher hops, maybe a harder boil, maybe an increase in flavour additions that increase the perception of bitterness.
Cheers
MAH
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